| First leg |
| Mat |
Date |
Local |
Goals |
Visitor |
| 1s | 29/08/10 | Real Sociedad | 1 - 0 | Villarreal C.F. [+] | | 2n | 12/09/10 | Villarreal C.F. [+] | - | Espanyol | | 3r | 19/09/10 | Levante | - | Villarreal C.F. [+] | | 4t | 22/09/10 | Villarreal C.F. [+] | - | Deportivo | | 5t | 26/09/10 | Málaga | - | Villarreal C.F. [+] | | 6t | 03/10/10 | Villarreal C.F. [+] | - | Racing | | 7t | 17/10/10 | Hércules CF | - | Villarreal C.F. [+] | | 8t | 24/10/10 | Villarreal C.F. [+] | - | At Madrid | | 9t | 31/10/10 | Sporting de Gijón | - | Villarreal C.F. [+] | | 10t | 07/11/10 | Villarreal C.F. [+] | - | Ath Bilbao | | 11t | 14/11/10 | FC Barcelona | - | Villarreal C.F. [+] | | 12t | 21/11/10 | Villarreal C.F. [+] | - | Valencia | | 13t | 28/11/10 | Zaragoza | - | Villarreal C.F. [+] | | 14t | 05/12/10 | Villarreal C.F. [+] | - | Sevilla | | 15t | 12/12/10 | Getafe | - | Villarreal C.F. [+] | | 16t | 19/12/10 | Villarreal C.F. [+] | - | Mallorca | | 17t | 02/01/11 | Villarreal C.F. [+] | - | Almería | | 18t | 09/01/11 | Real Madrid | - | Villarreal C.F. [+] | | 19t | 16/01/11 | Villarreal C.F. [+] | - | Osasuna | | 20t | 23/01/11 | Villarreal C.F. [+] | - | Real Sociedad | |
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| Second leg |
| Mat |
Date |
Local |
Goals |
Visitor |
| 21t | 30/01/11 | Espanyol | - | Villarreal C.F. [+] | | 22t | 06/02/11 | Villarreal C.F. [+] | - | Levante | | 23t | 13/02/11 | Deportivo | - | Villarreal C.F. [+] | | 24t | 20/02/11 | Villarreal C.F. [+] | - | Málaga | | 25t | 27/02/11 | Racing | - | Villarreal C.F. [+] | | 26t | 02/03/11 | Villarreal C.F. [+] | - | Hércules CF | | 27t | 06/03/11 | At Madrid | - | Villarreal C.F. [+] | | 28t | 13/03/11 | Villarreal C.F. [+] | - | Sporting de Gijón | | 29t | 20/03/11 | Ath Bilbao | - | Villarreal C.F. [+] | | 30t | 03/04/11 | Villarreal C.F. [+] | - | FC Barcelona | | 31t | 10/04/11 | Valencia | - | Villarreal C.F. [+] | | 32t | 17/04/11 | Villarreal C.F. [+] | - | Zaragoza | | 33t | 24/04/11 | Sevilla | - | Villarreal C.F. [+] | | 34t | 01/05/11 | Villarreal C.F. [+] | - | Getafe | | 35t | 08/05/11 | Mallorca | - | Villarreal C.F. [+] | | 36t | 11/05/11 | Almería | - | Villarreal C.F. [+] | | 37t | 15/05/11 | Villarreal C.F. [+] | - | Real Madrid | | 38t | 22/05/11 | Osasuna | - | Villarreal C.F. [+] | |
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